Fabrication of zinc oxide nanostructures via a low-temperature method and investigation of their photoluminescence properties
Abstract
ZnO nanorods were successfully synthesized by the low-temperature hydrothermal method on a grid formed by cross-weaving stainless-steel wires. Our method includes seeding process by simple dip-coating technique, followed by post annealing process and hydrothermal growth process of ZnO nanostructures. When the nanorods were synthesized a second time, their size increased and the maximum of the photoluminescence spectrum shifted toward the larger wavelength. It was observed that the shift of the PL emission band was associated with the increase in the size of the nanostructures. At the same time, the photoluminescence spectra of the samples showed an increase in the emission band associated with defects. Considering that the defect observed in the PL spectrum is interstitial oxygen, the increase in the emission band corresponding to this defect in the doubly synthesized samples indicates that they are a bulk defect.
Keywords:
About the Authors
List of references
Abdelkarem K., Saad R., El Sayed A.M., Design of high-sensitivity La-doped ZnO sensors for CO2 gas detection at room temperature. Sci Rep 13, 18398 (2023). https://doi.org/10.1038/s41598-023-45196-y
Rabisankar Dash, C. Mahender, Prasanta Kumar Sahoo, Ankur Soam, Preparation of ZnO layer for solar cell application, Materials Today: Proceedings, Volume 41, Part 2, 2021, Pages 161-164, https://doi.org/10.1016/j.matpr.2020.08.448.
A. Esbergenova, Interlinking the Fe doping concentration, optoelectronic properties, and photocatalytic performance of ZnO nanostructures, Curr. Appl. Phys. 2024, 67 18–29. https://doi.org/10.1016/j.cap.20 24.07.009.
Zhuxin Li, Wei Liu, Ru Wang, Feng Chen, Jinping Chen, Yizhi Zhu, Zengliang Shi, Chunxiang Xu, Interface design for electrically pumped ultraviolet nanolaser from single ZnO-nanorod, Nano Energy, Volume 93, 2022, 106832, https://doi.org/10.1016/j.nanoen.2021.106832.
Rodrigues J., Pereira S.O., Zanoni J., Rodrigues C., Brás M., Costa F.M., Monteiro T., ZnO Transducers for Photoluminescence-Based Biosensors: A Review. Chemosensors 2022, 10, 39. https://doi.org/10.339 0/chemosensors10020039.
Sagnik D., Uttam K.G., Rajib D., Chandan K.G., Mrinal P. White light phosphorescence from ZnO nanoparticles for white LED applications, New J. Chem., 2022,46, 17585-17595, https://doi.org/10.1039/ D2NJ02684H.
Dhirendra Kumar Sharma, Sweta Shukla, Kapil Kumar Sharma, Vipin Kumar, A review on ZnO: Fun- damental properties and applications, Materials Today: Proceedings, Volume 49, Part 8, 2022, Pages 3028-3035, https://doi.org/10.1016/j.matpr.2020.10.238.
Xie J, Li H, Zhang T, Song B, Wang X, Gu Z. Recent Advances in ZnO Nanomaterial-Mediated Biological Applications and Action Mechanisms. Nanomaterials (Basel). 2023 Apr 27;13(9):1500. https://doi.org/10.3390/nano13091500.
Eric Navarrete, Frank Güell, Paulina R. Martínez-Alanis, Eduard Llobet, Chemical vapour deposited ZnO nanowires for detecting ethanol and NO2, Journal of Alloys and Compounds, Volume 890, 2022, 161923, https://doi.org/10.1016/j.jallcom.2021.161923.
R.R. Jalolov, B.N. Rustamova, Sh.Z. Urolov, Z.Sh. Shaymardanov, High-temperature photoluminescence properties of various defects in hydrothermally grown ZnO microrods. Physica B 675 (2024) 415613. https://doi.org/10.1016/j.physb.2023.415613.
José Luis Clabel Huamán and Victor Anthony Garcia Rivera. Perovskite Ceramics Recent Advances and Emerging Applications (Elsevier, 2023). https://doi.org/10.1016/C2020-0-03937-X.
R.R. Jalolov, Sh.Z. Urolov, Z.Sh. Shaymardanov, S.S. Kurbanov, B.N. Rustamova, Complex features of the photoluminescence from ZnO nanorods grown by vapor-phase transport method, Materials Science in Semiconductor Processing 128 (2021) 105783. https://doi.org/10.1016/j.mssp.2021.105783.
K. Punia G., Lal S.Dalela, A comprehensive study on the impact of Gd substitution on structural, optical and magnetic properties of ZnO nanocrystals, Journal of Alloys and Compounds 868 (2021) 159142. https://doi.org/10.1016/j.jallcom.2021.159142.
Tokimori S., Funato K., Wada K., Matsuyama T., Okamoto K., Emission Enhancement of ZnO Thin Films in Ultraviolet Wavelength Region Using Au Nano-Hemisphere on Al Mirror Structures. Nanomaterials 2025, 15, 400. https://doi.org/10.3390/nano15050400.
A.C. García-Velasco, A. Báez-Rodríguez, M. Bizarro, R.M. Calderón-Olvera, J. Hernández-Torres, L. García-González, L. Zamora-Peredo, Surface defect-rich ZnO nanostructures with high yellow-orange luminescence, Journal of Luminescence, Volume 251,2022, 119187, https://doi.org/10.1016/j.jlumin.20 22.119187.
Kumar N., Poulose V., Laz Y.T., Chandra F., Abubakar S., Abdelhamid A.S., Alzamly A., Saleh N., Temperature Control of Yellow Photoluminescence from SiO2-Coated ZnO Nanocrystals. Nanomaterials 2022, 12, 3368. https://doi.org/10.3390/nano12193368.
Cai-Qin L., Si-Cong Z., Chi-Hang L., Francis Chi-Chung L., Ferromagnetic behavior of native point defects and vacancy-clusters in ZnO studied by first principle calculation, Mater. Res. Express. 2020. Vol. 7. 076103. https://doi.org/10.1088/2053-1591/aba14a.
Copyright (c) 2024 Р. Жалолов, Б. Рустамова (Автор)

This work is licensed under a Creative Commons Attribution 4.0 International License.