Semi-transparent organic solar cells based on D18 and DEH-X series prepared in different solvents
Abstract
This study investigates the optical and photovoltaic properties of D18 and DEH-X series donor polymers in semi-transparent organic solar cells (ST-OSCs). Active layers were prepared by mixing D18, DEH-3, DEH-10, DEH-20 donor polymers with L8-Bo acceptor in a 1:1 ratio by dissolving them in toluene and chloroform solvent. Absorption spectra, external quantum efficiency (EQE) and photovoltaic parameters, including short-circuit current (Jsc), open-circuit voltage (Voc), energy conversion efficiency (PCE) and average visible transmittance (AVT), were analyzed. The DEH-X series increases light absorption and improves charge transport, which improves the efficiency of the device.
Keywords:
About the Authors
List of references
Garg S., Goel N. Optoelectronic applications of conjugated organic polymers: influence of donor/acceptor groups through density functional studies //The Journal of Physical Chemistry C. – 2022. – . 126. – №.
22. – . 9313-9323.
Le T. Quantitative structure–property relationship modeling of diverse materials properties //Chemical reviews. – 2012. – . 112. – №. 5. – . 2889-2919.
Jonda C. Surface roughness effects and their influence on the degradation of organic light emitting devices
//Journal of Materials Science. – 2000. – . 35. – . 5645-5651.
Snaith H.J. Morphological and electronic consequences of modifications to the polymer anode ‘PEDOT: PSS’ //Polymer. – 2005. – . 46. – №. 8. – . 2573-2578.
Wang Z. Progress on extending the light absorption spectra of photocatalysts //Physical Chemistry Chemical Physics. – 2014. – . 16. – №. 7. – . 2758-2774.
Zhong X. et al. Facile Synthesis of Key Building Blocks of D18 Series Conjugated Polymers for High- Performance Polymer Solar Cells //ACS Applied Polymer Materials. – 2023. – . 5. – №. 3. – . 1937-1944.
Moliton A., Hiorns R. C. Review of electronic and optical properties of semiconducting -conjugated polymers: applications in optoelectronics //Polymer International. – 2004. – . 53. – №. 10. – . 1397-1412.
Li Y. Molecular design of photovoltaic materials for polymer solar cells: toward suitable electronic energy levels and broad absorption //Accounts of chemical research. – 2012. – . 45. – №. 5. – . 723-733.
Luo Y. et al. High-Efficiency Semi-Transparent Organic Solar Cells Using Pentacyclic Aromatic Lactam- Containing Terpolymer Strategy for Eco-Friendly Greenhouse Application //Solar RRL. – 2022. – . 6. –
№. 12. – . 2200679.
Li Y. Molecular design of photovoltaic materials for polymer solar cells: toward suitable electronic energy levels and broad absorption //Accounts of chemical research. – 2012. – . 45. – №. 5. – . 723-733.
KHOUSSA K., BOUBCHIR L., LEVEQUE P. Artificial Intelligence in Organic Photovoltaics: Predicting Power Conversion Efficiency from the Molecular Chemical Structure of (Donor/Acceptor) Pairs //Available at SSRN 4997197. – 2024.
Wang Z. Enhanced visible-light absorption and photocurrent generation of three-dimensional metal–dielectric hybrid-structured films //ACS Applied Energy Materials. – 2021. – . 4. – №. 10. – . 10542-10552.
Wei C. Morphology optimization via pre-aggregation and miscibility matching in PM6: L8-BO ternary organic solar cells //Physical Chemistry Chemical Physics. – 2024. – . 26. – №. 45. – . 28573-28585.
Sammelselg V. Composition and thickness determination of thin oxide films: comparison of different programs and methods //Journal of Analytical Atomic Spectrometry. – 1999. – . 14. – №. 3. – . 523-527.
Traverse C.J. Emergence of highly transparent photovoltaics for distributed applications //Nature Energy. – 2017. – . 2. – №. 11. – . 849-860.
Sammelselg V. Composition and thickness determination of thin oxide films: comparison of different programs and methods //Journal of Analytical Atomic Spectrometry. – 1999. – . 14. – №. 3. – . 523-527.
Hai P.N. Electromotive force and huge magnetoresistance in magnetic tunnel junctions //Nature. – 2009. –
. 458. – №. 7237. – . 489-492.
Wei C. Morphology optimization via pre-aggregation and miscibility matching in PM6: L8-BO ternary organic solar cells //Physical Chemistry Chemical Physics. – 2024. – . 26. – №. 45. – . 28573-28585.
Araujo G.L., Sanchez E. Analytical expressions for the determination of the maximum power point and the fill factor of a solar cell //Solar Cells. – 1982. – . 5. – №. 4. – . 377-386.
Hai P. N. Electromotive force and huge magnetoresistance in magnetic tunnel junctions //Nature. – 2009. – . 458. – №. 7237. – . 489-492.
Liu H. Transparent conducting oxides for electrode applications in light emitting and absorbing devices
//Superlattices and Microstructures. – 2010. – . 48. – №. 5. – . 458-484.
Andrievski R.A. Review of thermal stability of nanomaterials //Journal of materials science. – 2014. – .
49. – . 1449-1460.

This work is licensed under a Creative Commons Attribution 4.0 International License.